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the synthesis of complex biologically ..

of Tokyo )TABIRA,Hayami ; SHIBATA,Takanori ; SOAI,Kenso
2D639Asymmetric C-H Bond Activation (Tokyo Institute of Technology )MIKAMI,Koichi ; HATANO,Manabu ; TERADA,Masahiro
2D640Synthetic Study on (R)-2-Hydroxy-4-phenylbutyric acid ester (Ajinomoto Co., INC.)MATSUEDA,Hiroyuki ; NAKANO,Takashi ; TAKEDA,Hideo ; KURAUCHI,Masahiko ; IZAWA,Kunisuke
2D641Palladium-catalyzed Stereoselective Intramoleculer Cyclization (TOYAMA Univ.)YOKOYAMA,Hajime ; FUKUDA,Youko ; YAMAGUCHI,Seiji ; HIRAI,Yoshiro
2D642Total Synthesis of SS20846A via Intramolecular Palladium(II)-catalyzed Intramolecular Cyclization (TOYAMA Univ.)YOKOYAMA,Hajime ; OTAYA,Kumiko ; YAMAGUCHI,Seiji ; HIRAI,Yoshiro

(16:00-17:00)
2D643Diastereoselective Approach to (+)-Aspicilin Using Addition of Org anometallics to the Aldehyde Derived from meso-Tartaric Acid (Faculty of Engineering, Mie Univ.

Lucidi Chimica Organica Superiore 2 by Chimico …
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The auration of electron-deficient arenes has also been achieved. Aryl-gold(I) complexes only react with alkynesin the presence of a palladium(0) catalysts, or a palladium(II) precatalyst,to afford products of carboauration.The gold-catalyzed intermolecular hydroarylation of alkynesleadsto 1,1-disubstituted alkenes or 1,2-disubstituted derivatives in thecase of alkynes bearing electron-withdrawing groups.According to experimental and computational workon the cyclizationof arylalkynes catalyzed by platinum(II), two pathways with very similaractivation energies compete in intramolecular hydroarylations: a Friedel–Craftsalkenylation and a reaction proceeding through metal cyclopropyl carbenes. However, comparing the results obtained forplatinum(II)-catalyzed hydroarylation reactions such as the cyclizationof N-propargyl-N-tosyl anilines,better yields and milder reaction conditions are obtained with cationicgold(I) catalysts (Scheme ). A detailed theoretical analysis of the cycloisomerizationof phenyl propargyl ethers catalyzed by a Au38 clusterhas recently been reported.N-Butynyl anilines also form 1,2-dihydroquinolines by 6-exo-dig cyclization followed by a proton-catalyzed isomerizationof the exocyclic double bond. Theseproducts could be rearranged into functionalized indole derivativesunder photochemical conditions.

Dispense del corso di chimica organica superiore 2

Regio- and Stereospecific Synthesis of C-3 Functionalized Proline Derivatives by Palladium Catalyzed Directed C(sp 3)–H Arylation
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of Toyama) KOSHIBA, Ryoma; TAKAHASHI, Yu; HORINO, Yoshikazu; ABE, Hitoshi
Palladium-Catalyzed Three-Component Reaction of Ally boranes, Alkyl Boranes, and Aldehyde: Stereoselective Synthesis of Homoallylic alcohols (Grad.

Univ.) SUMINO, Shuhei; RYU, Ilhyong
Chair: HAYASHI, Minoru (09:00-10:00)
* 8:50-9:00: interval for laptop PC connection.(3B4-01, 3B4-02, 3B4-03, 3B4-04, 3B4-05, 3B4-06) DMF-Protected Palladium Nanoclusters Catalyzed Synthesis of 2,3-Disubstituted Indoles (Fac.

Serratosa defined Synthesis as a heuristic ..

Enantioselective CuH-Catalyzed Reductive Coupling of …
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Technol., Shinshu Univ.) SAKUMA, Daichi; NISHII, Yoshinori

Chair: AMAYA, Toru (15:50-16:50)
* 15:40-15:50: interval for laptop PC connection.(1B6-42, 1B6-43, 1B6-44, 1B6-45, 1B6-46, 1B6-47) Asymmetric formal [3+2] cycloadditions of (E)-nitrones with -keto esters using nickel-diamine catalysts: effect of achiral base and mechanistic insights (RIKEN) NAKAMURA, Genta; SOHTOME, Yoshihiro; SYLVAIN, Lectard; TSUCHIMOTO, Teruhisa; SODEOKA, Mikiko
Asymmetric aerobic -hydroxylation of oxindoles using palladium catalyst (RIKEN) HOJO, Daiki; AKINDELE, Tito; SOHTOME, Yoshihiro; SODEOKA, Mikiko
Synthesis of multi-substituted alkenes through iron-catalyzed carboalumination of alkynes (RCMS, Nagoya Univ.; Grad.

Eng., Nagoya Univ.) MIYAKE, Yoshihiro
Chair: FUJIHARA, Tetsuaki (13:30-14:30)
* 13:20-13:30: interval for laptop PC connection.(2B4-28, 2B4-30, 2B4-31, 2B4-32, 2B4-33)* Modular Synthesis of Triarylmethanes through Palladium-Catalyzed Sequential Arylation of Methyl Phenyl Sulfone (WPI-ITbM, Nagoya Univ.) NAMBO, Masakazu; CRUDDEN, Cathleen M.
Allylic Arylation of Allyloxyphenylboronic Acid Pinacol Esters Using Hydrazone-Palladium Catalyst (Grad.

propargyl alcohol Publications and Abstracts | …
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  • Strategies and Tactics in Organic Synthesis ..

    issuu ..

  • 2015 | Research groups | Imperial College London

    These intermediates were used to prepare three discrete stereo- and regioisomers of ..

  • Organocatalysis: Key Trends in Green Synthetic …

    A novel palladium-catalyzed ..

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.68 stereo - and regio-isomers ..

Faculty of Science and Technology )OHI,Katsuhide ; SHIMA,Kyoko ; HAMADA,Kozue ; SAITOH,Yoshio ; NISHIYAMA,Shigeru ; YAMAMURA,Shousuke
3E712Palladium-catalyzed stereoselective syntheses of methyl -(E,E)-5 hydroxy-6-methyl-8-phenylocta-2,7-dienoate and pironetin.(Waseda Univ.)FURUYAMA,Masaaki ; OHSHIBA,Makiko ; SHIMIZU,Isao

(11:00-12:00)
3E713 Session LectureGlutamate transporter inhibitors()SHIMAMOTO,Kazuko
3E716 Session LectureDevelopment of antifoulins agents and biofoeling mechanism()SHIZURI,Yoshikazu

(13:00-14:00)
3E725Synthetic Studies on Obtusenynes (Graduate School of Science, Hokkaido Univ.)FUJIWARA,Kenshu ; AWAKURA,Daisuke ; MURAI,Akio
3E7268-endo selective cyclization of hydroxy epoxides (Graduate School of Science, Hokkaido Univ.)FUJIWARA,Kenshu ; MISHIMA,Hirofumi ; AMANO,Arika ; TOKIWANO,Tetsuo ; MURAI,Akio
3E727Synthesis of Fused Bicyclic Ether Compounds by Cyclization of Diepoxy Alcohols (Graduate School of Science, Hokkaido Univ.

that stereo- and regio-selectivity is ..

)KUWANO,Ryoichi ; ITO,Yoshihiko
1D730Transition Metal Catalyzed Dehydrogenative Silylation of Ketones (Sagami Chemical Research Center )IGARASHI,Mamoru ; SUGIHARA,Yuichi ; FUCHIKAMI,Takamasa

(14:00-14:50)
1D731Highly Regioselective Addition of Selenols to Allenes Catalyzed by Palladium Complexes (Osaka Univ.)OGAWA, Akiya ; KUDO, Atsuko ; HIRAO, Tosikazu
1D732Highly Regioselective Addition of Thiols to Acetylenes Catalyzed b y Rhodium Complexes (Osaka Univ.;Kansai Univ.)OGAWA, Akiya ; IKEDA, Takuma ; SONODA,Noboru ; HIRAO, Toshikazu
1D733A Stereoselective Synthesis of Silyl Enol Ethers Using Iridium-catalyzed Hydorogen Migrations (Graduate School of Engineering, Hokkaido Univ.)OHMURA,Toshimichi ; YAMAMOTO,Yasunori ; MIYAURA,Norio
1D734Aldol Type Coupling Catalyzed by Iridium(I) Cation Complexes (Nagoya Univ.

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)KOMIYA,Naruyoshi ; KUMANO,Tatsuyuki ; MURAHASHI,Shun-Ichi

(9:00-10:00)
3C301Synthesis of (Silyl)(boryl)imines by Silaboration of Isonitriles (Kyoto Univ.)SUGINOME,Michinori ; FUKUDA,Takeshi ; NAKAMURA,Hiroshi ; ITO,Yoshihiko
3C302Nickel-Catalyzed Silaborative Dimerization of Alkynes (Kyoto Univ.)SUGINOME,Michinori ; MATSUDA,Takanori ; ITO,Yoshihiko
3C303Platinum- Catalyzed Regio- and Stereo-Selective Silaborative Coupling of Dienes to Aldehydes (Kyoto Univ.)SUGINOME,Michinori ; NAKAMURA,Hiroshi ; MATSUDA,Takanori ; ITO,Yoshihiko
3C304Palladium-Catalyzed Borylation of Aryl Triflates with Pinacolborane (Kitami Institute of Technology )MURATA,Miki ; WATANABE,Shinji ; MASUDA,Yuzuru
3C305Palladium-Catalyzed Cross-Coupling Reaction of Diboron with Allyl Halides (Hokkaido Univ.

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